Intermolecular hydrophosphination of alkynes and related carbon-carbon multiple bonds catalyzed by organoytterbiums

…, K Komeyama, M Takeda, T Shishido…

Index: Takaki, Ken; Koshoji, Go; Komeyama, Kimihiro; Takeda, Mitsuhiro; Shishido, Tetsuya; Kitani, Akira; Takehira, Katsuomi Journal of Organic Chemistry, 2003 , vol. 68, # 17 p. 6554 - 6565

Full Text: HTML

Citation Number: 85

Abstract

Intermolecular hydrophosphination of alkynes with diphenylphosphine is catalyzed by a Yb- imine complex,[Yb (η2-Ph2CNPh)(hmpa) 3], to give alkenylphosphines and phosphine oxides after oxidative workup in good yields under mild conditions. This reaction is also ...

Related Articles:

Copper??Catalyzed Synthesis of Alkylphosphonates from H??Phosphonates and N??Tosylhydrazones

[Miao, Wenjun; Gao, Yuzhen; Li, Xueqin; Gao, Yuxing; Tang, Guo; Zhao, Yufen Advanced Synthesis and Catalysis, 2012 , vol. 354, # 14-15 p. 2659 - 2664]

Reactivity Diversification–Synthesis and Exchange Reactions of Cobalt and Iron 2??Alkenylpyridine/??pyrazine Complexes Obtained by Vinylic C (sp2)–H Activation

[Turnblom,E.W.; Katz,T.J. Journal of the American Chemical Society, 1973 , vol. 95, p. 4292 - 4311]

Reactivity Diversification–Synthesis and Exchange Reactions of Cobalt and Iron 2??Alkenylpyridine/??pyrazine Complexes Obtained by Vinylic C (sp2)–H Activation

[Turnblom,E.W.; Katz,T.J. Journal of the American Chemical Society, 1973 , vol. 95, p. 4292 - 4311]

Reactivity Diversification–Synthesis and Exchange Reactions of Cobalt and Iron 2??Alkenylpyridine/??pyrazine Complexes Obtained by Vinylic C (sp2)–H Activation

[Turnblom,E.W.; Katz,T.J. Journal of the American Chemical Society, 1973 , vol. 95, p. 4292 - 4311]

TERTIÄRE PHOSPHINOXIDE AUS DIPHENYLCHLORPHOSPHIN UND CARBONSÄUREN

[Sartori, Peter; Mosler, Gerhard Phosphorus and Sulfur and the Related Elements, 1980 , vol. 8, p. 115 - 120]

More Articles...