Canadian Journal of Chemistry

Spectral and Chemical Properties of Β-and γ-Functional Silanes

AG Brook, JB Pierce

Index: Brook,A.G.; Pierce,J.B. Canadian Journal of Chemistry, 1964 , vol. 42, p. 298 - 304

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Citation Number: 30

Abstract

The synthesis of β-and γ-hydroxy-and keto-silanes is described, together with that of their carbon analogues. Unlike the α-isomers, the hydroxysilanes do not rearrange to silyl ethers, and the ultraviolet spectra of the silyl ketones is essentially the same as those of the carbon analogues, and unlike that of α-silyl ketones. β-Silyl ketones have a carbonyl-stretching frequency midway between that of ordinary ketones and α-silyl ketones. These effects are ...