Boron-nitrogen compounds: XCVIII. Preparation and reactions of 2-(azol-1′-yl)-1, 3, 2-diazaboracycloalkanes
F Alam, K Niedenzu
Index: Alam, Fazlul; Niedenzu, Kurt Journal of Organometallic Chemistry, 1983 , vol. 243, # 1 p. 19 - 30
Full Text: HTML
Citation Number: 8
Abstract
Abstract The preparation of several 1, 3-dimethyl-2-(azol-l′-yl)-1, 3, 2- diazaboracyclohexanes is described and their NMR spectra are interpreted. The reaction of 2-(pyrazol-1′-yl)-1, 3, 2,-diazaboracyclohexanes with pyrazoles was found to lead to 1/1 molar adducts which exist in equlibrium with the uncomplexed species, whereas B- tetraalkylpyrazaboles are obtained on reaction with (dimethylamino) dialkylboranes. ...
Related Articles:
Boron-nitrogen compounds. Part 117. Pyrazaboles of the type RR'B (. mu.-pz) 2BRR'and related studies
[Das, M. K.; DeGraffenreid, A. L.; Edwards, K. D.; Komorowski, L.; Mariategui, J. F.; et al. Inorganic Chemistry, 1988 , vol. 27, p. 3085 - 3089]