Journal of the American Chemical Society

The Carbonylation of Organoboranes. I. The Carbonylation of Trialkylboranes. A Novel Synthesis of Trialkylcarbinols

MED Hillman

Index: Hillman,M.E.D. Journal of the American Chemical Society, 1962 , vol. 84, p. 4715 - 4720

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Citation Number: 49

Abstract

Reactions of carbon monoxide with trialkylboranes have been discovered which gave a variety of novel products, depending on reaction temperature and solvent. Hexaalkyl-2, S- diboradioxanes and trialkylcarbinylboronic acids or anhydrides were obtained in near- ...