Highly fluorinated acetylenes. Preparation and some cyclization reactions

RJ De Pasquale, CD Padgett…

Index: De Pasquale,R.J. et al. Journal of Organic Chemistry, 1975 , vol. 40, p. 810 - 811

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Citation Number: 28

Abstract

Summary: Simplified preparations of new highly fluorinat- ed acetylenes are described and a representative model undergoes thermal cycloaddition reactions to afford a cy- clohexadiene, triazole, and cyclobutene. ... Sir: Highly fluorinated acetylenes have been prepared pre- viously by multistep synthetic routes1 that invariably in- ... J. Org. Chem., V d . 40, No. 6, 1975 81 1 ... H,I + PhCH=CHBr - &CH=CHPh - &C=CPh In 1. 11 2. 111 70-95% ...

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