Journal of the American Chemical Society

Cyclic Dienes. XX. 4-n-Octyl-1, 2-dimethylenecyclohexane1

WJ Bailey, WA Klein

Index: Bailey; Klein Journal of the American Chemical Society, 1957 , vol. 79, p. 3124,3127

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Citation Number: 6

Abstract

A convenient synthesis of a 2-alkyl-1.3-butadiene was developed from a commercially available alkenylsuccinic anhydride as the starting material. Thus 2-n-octyl-1, 3-butadiene was prepared in four steps including a pyrolysis of a diacetate in an over-all yield of 53%. This 2-octylbutadiene was then converted in five steps to 4-n-octyl-1, 2- dimethylenecyclohexane in an over-all yield of 40%. The final step in the synthesis ...