Synthesis of isolable thiirane-2-thione (α-dithiolactone) from thioketene s-oxide

K Okuma, T Shigetomi, Y Nibu, K Shioji…

Index: Schaumann, Ernst Chemische Berichte, 1982 , vol. 115, p. 2755 - 2765

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Citation Number: 26

Abstract

... Volume: Page: ... By means of geometry optimization of the 6-31G(d,p) basis set, 1a was calculated to be 56.4 and 79.7 kJ/mol ... 11 Schaumann and Behrens reported the synthesis of α-thiolactone by oxidation of thioketenes (C−S bond lengths: 1.916 and 1.726 Å). ...