Journal of Organometallic Chemistry

Metal derivatives of amidoximes I. Mono-, bis-and tris-(trimethylsilyl) amidoximes

AB Goel, VD Gupta

Index: Goel,A.B.; Gupta,V.D. Journal of Organometallic Chemistry, 1974 , vol. 72, p. 171 - 177

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Abstract

Oxime and hydroxylamine derivatives of metals are of current interest [11. Chelating oximes such as amidoximes [2], R (Hz N) C= N-OH, were synthesized during the end of the last century, but little attention was given to their metal derivatives apart from their analytical applications [3-53. We report the synthesis of new mono-, bis-and tris-(trimethylsilyl) amidoximes. Trimethylchlorosilane reacted readily at room temperature with amidoximes, ...