Reaction of alkoxyhydroperoxides with metal salts alkyl halide preparation

…, JAM Laan, FP Van Lier, D van der Steen, JP Ward

Index: Cardinale, G.; Grimmelikhuysen, J. C.; Laan, J. A. M.; Lier, F. P. van; Steen, D. van der; Ward, J. P. Tetrahedron, 1989 , vol. 45, # 18 p. 5971 - 5978

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Citation Number: 5

Abstract

A synthesis is described of alkyl chlorides by reaction of methoxy hydroperoxides, prepared from 1-alkenes by ozonisation in methanol, with ferric chloride: RCH CH2→ RCH (OOH) OCH3→ R·→ RC1. Yields of 1-chlorotetradecane were about 60%; those of other halides ...