Spin trapping of fluoroalkyl radicals
L Gille, R Stoesser
Index: Gille, Lars; Stoesser, Reinhard Journal of Fluorine Chemistry, 1994 , vol. 69, # 2 p. 191 - 194
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Citation Number: 9
Abstract
Abstract The formation of fluoroalkyl radicals in liquid chlorofluorocarbons (CF 2 Cl-CFCl 2, CFCl 3, CFCl 2-CH3, CHF 2-CF 2-CF 2 Cl, CF 3-CFH-CF 3 and CCl 4) has been investigated by means of the spin trapping technique and ESR spectroscopy. It is shown that the primary fluoroalkyl radicals which were generated in these compounds by ionising radiation are preferably formed by bond cleavage at carbon atoms attached to one ...
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