Hofmann rearrangement of carboxamides mediated by hypervalent iodine species generated in situ from iodobenzene and oxone: Reaction scope and limitations

AA Zagulyaeva, CT Banek, MS Yusubov…

Index: Andruszkiewicz, Ryszard; Gronek, Ewa; Haluszczak, Jolanta Synthetic Communications, 2008 , vol. 38, # 6 p. 905 - 913

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Citation Number: 47

Abstract

... Volume: Page: ... a All reactions of amides 8a−f (1 mmol) were performed at room temperature in the presence of PhI (1 equiv) and Oxone (2 equiv) in CH 3 CN−H 2 O (1:1, v/v) (6 mL). b ... chem. and is now firmly established as a versatile synthetic reagent. ...