Oxidative cleavage of S??arylmercaptoacetic acids by sodium perborate: Kinetic and correlation study

…, K Pandiarajan, K Krishnasamy…

Index: Kabilan, S.; Pandiarajan, K.; Krishnasamy, K.; Sankar, P. International Journal of Chemical Kinetics, 1995 , vol. 27, # 5 p. 443 - 452

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Citation Number: 12

Abstract

Abstract Kinetics of oxidation of twenty six S-arylmercaptoacetic acids (SAMA)(I) by sodium perborate (PB) have been studied in acid medium. The product of oxidation is the corresponding thiophenol. The rate data of meta-and para-substituted acids have been correlated with DSP equations. While the para-compounds correlate well with σ I and σ R values, the meta-compounds correlate well with σ I and σ math image values. The reaction ...