Non-heme iron catalysis in CC, C–H, and CH 2 oxidation reactions. Oxidative transformations on terpenoids catalyzed by Fe (bpmen)(OTf) 2
D Clemente-Tejeda, A López-Moreno, FA Bermejo
Index: Clemente-Tejeda, David; Lopez-Moreno, Alejandro; Bermejo, Francisco A. Tetrahedron, 2013 , vol. 69, # 14 p. 2977 - 2986
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Citation Number: 15
Abstract
The oxidation of terpene olefins with hydrogen peroxide in the presence of the non-hemo catalyst 5a afforded mixtures of epoxides whose composition was dependent upon the oxidation protocol used in each case. With terpenoid enones, the mixtures obtained evolved from clean epoxidation of α-ionone 23 to the clean allylic oxidation of damascone 28 due to the progressive deactivation of the electron density on the double bonds present in this ...
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