Twofold Carbon–Carbon Bond Formation by Intra??and Intermolecular Radical Reactions of Aryl Diazonium Salts

H Jasch, Y Landais, MR Heinrich

Index: Jasch, Hannelore; Landais, Yannick; Heinrich, Markus R. Chemistry - A European Journal, 2013 , vol. 19, # 26 p. 8411 - 8416

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Citation Number: 20

Abstract

Aryl radicals are known as highly reactive intermediates.[1] For intermolecular reactions, especially for Meerwein-[2] or Gomberg–Bachmann-type [3] functionalizations of nonactivated alkenes or arenes, special precautions usually have to be undertaken to prevent undesired side reactions, such as hydrogen abstraction from the solvent.[4] The most common countermeasure hereby is to employ the alkene or arene in high excess, in ...