Reaction of Carbon Disulfide with Azide Ion1

E Lieber, E Oftedahl, CNR Rao

Index: Lieber,E. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 194 - 199

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Citation Number: 38

Abstract

Carbon disulfide reacts with azide ion to form the 1, 2, 3, 4-thiatriazolinethionate ion and not the acyclic azido. dithiocarbonate ion as previously reported. A series of salts of thiatriazoline have been prepared and none shows evidence for the presence of the azido group. Esters of thiatriazolinethione prepared by the reaction of the sodium salt with alkyl or acyl halides have been found to be either 5-(substituted) mercapto-1, 2, 3, 4-thiatri-azoles ...