Scandium triflate catalyzed allylation of acetals and gem-diacetates: a facile synthesis of homoallyl ethers and acetates
JS Yadav, BVS Reddy, P Srihari
Index: Yadav, Jhillu S.; Subba Reddy, Basi V.; Srihari Synlett, 2001 , # 5 p. 673 - 675
Full Text: HTML
Citation Number: 55
Abstract
Abstract: Scandium triflate catalyzes efficiently the allylation reactions of acetals and gem- diacetates with allyltrimethylsilane at ambient temperature to afford the corresponding homoallyl ethers and acetates in high yields. Also it is found to be effective for the direct formation of homoallyl ethers from aldehydes and allylsilane in presence of trimethylorthoformate. Key words: scandium triflate, allyltrimethylsilane, homoallyl ethers, ...
Related Articles:
Barbier-type allylation of acetals with allyl bromide in a Pb/Al bimetal redox system
[Tanaka,Hideo; Yamashita, Shiro; Ikemoto, Youichi; Torii, Sigeru Tetrahedron Letters, 1988 , vol. 29, # 14 p. 1721 - 1724]
[Jung, Michael E.; Maderna, Andreas Tetrahedron Letters, 2004 , vol. 45, # 27 p. 5301 - 5304]
Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals
[Matsumoto, Kouichi; Ueoka, Koji; Suzuki, Shinkiti; Suga, Seiji; Yoshida, Jun-ichi Tetrahedron, 2009 , vol. 65, # 52 p. 10901 - 10907]
[Fuerstner, Alois; Voigtlaender, David Synthesis, 2000 , # 7 p. 959 - 969]
[Merisor, Elena; Conrad, Juergen; Malakar, Chandi C.; Beifuss, Uwe Synlett, 2008 , # 6 p. 903 - 907]