Synthesis, Rhodium Complexes and Catalytic Applications of a New Water??Soluble Triphenylphosphane??Modified β??Cyclodextrin

…, N Six, C Slomianny, H Bricout, S Tilloy…

Index: Legrand, Francois-Xavier; Six, Natacha; Slomianny, Christian; Bricout, Herve; Tilloy, Sebastien; Monflier, Eric Advanced Synthesis and Catalysis, 2011 , vol. 353, # 8 p. 1325 - 1334

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Citation Number: 17

Abstract

Abstract A new triphenylphosphane based on a β-cyclodextrin skeleton (PM-β-CD-OTPP) was synthesized. This ligand can be dispersed in water by using the nanoprecipitation method. Transmission electron microscopy and NMR spectroscopy showed that PM-β-CD- OTPP is aggregated in water and forms a stable dispersion. Its aqueous solubility can be dramatically increased in the presence of selected water-soluble guests by formation of ...