Ionic liquid oxidant for efficient and selective oxidation of benzylic alcohols
R Hosseinzadeh, M Mohadjerani…
Index: Hosseinzadeh, Rahman; Mohadjerani, Maryam; Tajbakhsh, Mahmood; Nouzarian, Mahboobe Synthetic Communications, 2011 , vol. 41, # 12 p. 1725 - 1732
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Abstract
Abstract Hexamethylenebis (N-methylimidazolium) dichlorochromate was easily prepared by addition of N-methylimidazole to 1, 6-dibromohexane to form the corresponding dibromide salt and subsequent treatment with CrO3 in 6 N HCl solution. It is a low-melting orange salt that selectively oxidized benzylic alcohols.
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