Journal of Organometallic Chemistry

Reactions of (chloromethyl) pentamethyldisilane with some nucleophilic reagents

M Kumada, M Ishikawa, K Tamao

Index: Kumada,M. et al. Journal of Organometallic Chemistry, 1966 , vol. 5, p. 226 - 232

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Citation Number: 8

Abstract

Abstract (Chloromethyl) pentamethyldisilane (I) underwent intramolecular rearrangement when treated with sodium methoxide, isopropoxide and phenoxide to give the corresponding alkoxypentamethyldisilylmethanes (CH 3) 3 SiCH 2 Si (CH 3) 2 OR, whereas it gave only substitution products of the formula (CH 3) 3 SiSi (CH 3) 2 CH 2 Y when allowed to react with sodium ethylmercaptide and thiophenolate, and with diethylamine and ...