Highly enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes using dipalladium complexes as precatalysts
TM Konrad, JA Fuentes, AMZ Slawin…
Index: Konrad, Tina M.; Fuentes, Jose A.; Slawin, Alexandra M. Z.; Clarke, Matthew L. Angewandte Chemie - International Edition, 2010 , vol. 49, # 48 p. 9197 - 9200
Full Text: HTML
Citation Number: 42
Abstract
Carboxylic acids make up a significant proportion of the commercially available chiral building blocks. An optimized process that produces enantioenriched carboxylic acids from readily available, cheap chemicals without the need for resolution is highly desired. One of the more important developments in catalysis in recent years has been the development of palladium catalyzed carbonylation of ethylene into a large scale highly productive ...
Related Articles:
[Ohtaka, Atsushi; Kono, Yuki; Inui, Shigeki; Yamamoto, Syusei; Ushiyama, Tomoki; Shimomura, Osamu; Nomura, Ryoki Journal of Molecular Catalysis A: Chemical, 2012 , vol. 360, p. 48 - 53]
Oxidation of benzoins to benzoic acids using sodium hydride under oxygen atmosphere
[Kang, Sunhae; Joo, Cheonik; Kim, Sun Min; Han, Hogyu; Yang, Jung Woon Tetrahedron Letters, 2011 , vol. 52, # 4 p. 502 - 504]
KMnO4-mediated oxidation as a continuous flow process
[Sedelmeier, Joerg; Ley, Steven V.; Baxendale, Ian R.; Baumann, Marcus Organic Letters, 2010 , vol. 12, # 16 p. 3618 - 3621]
Facile and Selective Deallylations of Esters under 'Aqueous' Free-Radical Conditions
[Perchyonok, V. Tamara; Ryan, Sarah J.; Langford, Steven J.; Hearn, Milton T.; Tuck, Kellie L. Synlett, 2008 , # 8 p. 1233 - 1235]
[Park, Cheon Min; Kwon, Min Serk; Park, Jaiwook Synthesis, 2006 , # 22 p. 3790 - 3794]