The Journal of Organic Chemistry

Synthesis of Some Triphenylphosphinalkylimines and Mono-and Dialkylaminotriphenylphosphonium Halides

H Zimmer, G Singh

Index: Zimmer,H.; Singh,G. Journal of Organic Chemistry, 1963 , vol. 28, p. 483 - 486

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Citation Number: 78

Abstract

The syntheses of some triphenylphosphinalkylimines and their addition reactions with alkyl halides to yield mono-and dialkylaminotriphenylphosphonium halides are reported. The limitation of alkyl halide addition reactions has been described. Sterically hindered t- butylmethylamine and f-butylethylamine have been prepared through the hydrolysis of the corresponding dialkylaminotriphenylphosphonium halides.