Hydrochalcogenation of activated olefines. Synthesis of functionalized dialkylchalcogenides
JV Comasseto, RA Gariani, JL Princival…
Index: Comasseto, Joao V.; Gariani, Rogerio A.; Princival, Jefferson L.; Dos Santos, Alcindo A.; Zinn, Fabiano K. Journal of Organometallic Chemistry, 2008 , vol. 693, # 17 p. 2929 - 2936
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Citation Number: 17
Abstract
Alkanethiols, selenols and tellurols are generated in situ by reaction of elemental sulfur, selenium and tellurium with commercial alkyllithiums, followed by reaction with deoxygenated water. The alkanechalcogenols react in situ with activated olefins in a Michael-type addition reaction.
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