Fischer Indole Synthesis with Organozinc Reagents

…, ZG Zhang, JS Li, P Knochel

Index: Haag, Benjamin A.; Zhang, Zhi-Guang; Li, Jin-Shan; Knochel, Paul Angewandte Chemie - International Edition, 2010 , vol. 49, # 49 p. 9513 - 9516

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Citation Number: 38

Abstract

Indoles (1) are an important class of N-heterocycles present in many natural products and pharmaceuticals.[1] Their synthesis presents a great challenge, and a range of new synthetic approaches to indoles have been reported in recent years.[2] Metal-catalyzed or- mediated methods have proved to be especially useful.[3] The classical Fischer indole synthesis [4] starting from aryl hydrazines [5, 6] 2 and ketones 3 is still extensively used, ...

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