DNA vs. Mirror??Image DNA: A Universal Approach to Tune the Absolute Configuration in DNA??Based Asymmetric Catalysis

…, S Vonhoff, S Klussmann, JJ Vasseur…

Index: Wang, Jocelyn; Benedetti, Erica; Bethge, Lucas; Vonhoff, Stefan; Klussmann, Sven; Vasseur, Jean-Jacques; Cossy, Janine; Smietana, Michael; Arseniyadis, Stellios Angewandte Chemie - International Edition, 2013 , vol. 52, # 44 p. 11546 - 11549 Angew. Chem., 2013 , vol. 125, # 44 p. 11760 - 11763

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Citation Number: 29

Abstract

Since the seminal work of Roelfes and Feringa in 2005,[1] DNA-based asymmetric catalysis has drawn increasing attention to become a particularly attractive tool for synthetic organic chemists. Indeed, DNA-based catalysts have now been successfully applied to a variety of asymmetric transformations including Diels–Alder cycloadditions,[1] Michael additions,[2] Friedel–Crafts alkylations,[3] fluorinations,[4] and syn-hydrations.[5, 6] More recently, the ...