The Journal of Organic Chemistry

Novel symmetrical and mixed carbamoyl and aminopolysulfanes by reactions of (alkoxydichloromethyl) polysulfanyl substrates with N-methylaniline

AL Schroll, G Barany

Index: Schroll, Alayne L.; Barany, George Journal of Organic Chemistry, 1986 ,  vol. 51,  # 10  p. 1866 - 1881

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Citation Number: 28

Abstract

Reactions of (alkoxydichloromethy1) polysulfanes with N-methylaniline can be rationalized by a" carbamoyl" route where the alkoxydichloromethyl group behaves via loss of alkyl chloride as a" masked" acid chloride or by a" sulfenyl" route which reflects fragmentation of the (alkoxydichloromethy1) polysulfanyl functionality into the corresponding alkoxy (thiocarbony1) and sulfenyl components (cf. Scheme I). Application of this and related ...