Canadian Journal of Chemistry

SYNTHESIS OF SYMMETRICAL AND UNSYMMETRICAL DIALKYLPHOSPHINOUS CHLORIDES

JL Ferron

Index: Ferron,J.L. Canadian Journal of Chemistry, 1961 , vol. 39, p. 842 - 845

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Citation Number: 8

Abstract

A series of compounds with the generalized formula RR'PCl have been obtained by the metal (antimony or zinc) reduction of [RR'PCl2]+[AlCl4]-. The yields of symmetrical and unsymmetrical dialkylphosphinous chlorides obtained by this method are superior to those obtained in previous syntheses.

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