Irreversible and highly enantioselective acylation of 2-halo-1-arylethanols in organic solvents catalyzed by a lipase from Pseudomonas fluorescens
J Hiratake, M Inagaki, T Nishioka…
Index: Hiratake, Jun; Inagaki, Minoru; Nishioka, Takaaki; Oda, Jun'ichi Journal of Organic Chemistry, 1988 , vol. 53, # 26 p. 6130 - 6133
Full Text: HTML
Citation Number: 88
Abstract
Figure 1. Lipase-catalyzed transesterification of 1-hexanol with vinyl acetate (O), isopropenyl acetate (O), vinyl butyrate (A), vinyl octanoate (w), 2, 2, 2-trichloroethyl acetate (A), and ethyl acetate (0). Conditions: 1-hexanol (10 mmol), enol esters 1 (10.5 mmol), lipase Amano P (500 mg), dry diisopropyl ether (20 mL), 25" C. Detection: GC (2% XE-60, 2 m, 70" C, ethyl benzene as internal standard).
Related Articles:
[Hagishita, Sanji; Seno, Kaoru; Kamata, Susumu; Haga, Nobuhiro; Ishihara, Yasunobu; Ishikawa, Michio; Shimamura, Mayumi Bioorganic and Medicinal Chemistry, 1997 , vol. 5, # 7 p. 1433 - 1446]
[Hagishita, Sanji; Seno, Kaoru; Kamata, Susumu; Haga, Nobuhiro; Ishihara, Yasunobu; Ishikawa, Michio; Shimamura, Mayumi Bioorganic and Medicinal Chemistry, 1997 , vol. 5, # 7 p. 1433 - 1446]
[Hagishita, Sanji; Seno, Kaoru; Kamata, Susumu; Haga, Nobuhiro; Ishihara, Yasunobu; Ishikawa, Michio; Shimamura, Mayumi Bioorganic and Medicinal Chemistry, 1997 , vol. 5, # 7 p. 1433 - 1446]