Diverse Reactivity of the cyclo-Diphosphinophosphonium Cation [(P t Bu) 3Me]+: Parallels with Epoxides and New catena-Phosphorus Frameworks

APM Robertson, CA Dyker, PA Gray…

Index: Deng, Robert M. K.; Dillon, Keith B. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 1911 - 1916

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Citation Number: 4

Abstract

... Journal of the ... 1 J P–P interactions, that is, 250 < J < 400 Hz,(14-16) and three longer range (2 × 2 J and 1 × 3 J) P–P interactions. ... In addition, we note that compounds 4a/b are isolobal inorganic models for the protonated intermediates invoked in acid-catalyzed ring-opening of ...