Preparation and chemistry of some pentasubstituted phosphorus compounds

DB Denney, DZ Denney, BC Chang…

Index: Denney,D.B. et al. Journal of the American Chemical Society, 1969 , vol. 91, p. 5243 - 5246

Full Text: HTML

Citation Number: 29

Abstract

Abstract: A series of trisubstituted phosphorus compounds have been allowed to react with diethyl peroxide. Materials with only phenyl and ethoxy groups bonded to phosphorus react to give pentasubstituted phosphorus compounds. The compound diphenyltriethoxyphosphorane undergoes pseudorotation at room temperature. At-60" pseudorotation has been slowed sufficiently so that two kinds of ethoxy groups are ...