Organometallics

Preparation of organofunctional bis (stannyl) methanes. Intramolecular coordination in the halo derivatives

HG Kuivila, TJ Karol, K Swami

Index: Kuivila, Henry G.; Karol, Thomas J.; Swami, Kamal Organometallics, 1983 , vol. 2, p. 909 - 914

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Citation Number: 27

Abstract

The preparation of a series of 3, 3-bis (trimethylstannyl)-, 3, 3-bis (halodimethylstannyl)-, and 3, 3-bis-(dihalomethybtanny1) propyl derivatives having carboxyl, hydroxy, acetoxy, and sulfoxy as functional groups is described. Intramolecular coordination in the bromostannyl acetates and sulfoxides was examined. 3, 3-Bis (bromodimethylstanny1) propyl acetate showed no evidence of coordination in the solid state or in acetonitrile as shown by IR ...