Synthesis of diethyl trimethylsilyl (trimethylsilylimido) phosphate

MA Pudovik, SA Terent'eva, AN Pudovik

Index: Pudovik; Terent'eva Russian Journal of General Chemistry, 2003 , vol. 73, # 6 p. 993 - 993

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Abstract

At present two methods of synthesis of dialkyl trimethylsilyl (trimethylsilylimido) phosphates have been described: exhaustive silylation of dialkyl imidophosphate with chlorotrimethylsilane in the presence of bases and the reaction of phosphorus acid chlorides with sodium or lithium bis (trimethylsilyl) amides [1, 2]. According to published data, the reaction of dialkyl (aryl) chlorophosphates with hexamethyldi silazane is accompanied by ...