The Journal of Organic Chemistry

Reactions of enamines with electrophilic sulfur compounds

ME Kuehne

Index: Kuehne,M.E. Journal of Organic Chemistry, 1963 , vol. 28, p. 2124 - 2128

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Citation Number: 40

Abstract

The reaction of 1-pyrrolidinocyclohexene and arylsulfonyl chlorides led, on hydrolysis, to 2- arylsulfonylcyclohexanones. With o-, m-, or p-nitrobeneenesulfenyl chloride, 2-mono-and 2, 6-biS (O-, m-, and p-nitrophenylsulfeny1) cyclohexanones were obtained. Intermediate bisnitrophenylsulfenyl enamines were isolated. Only monosubstitution products were obtained from 1-pyrrolidinocyclohexene and m-or p-nitrophenyl disulfides and from 6- ...