Canadian Journal of Chemistry

PERFLUOROALKYL ARSENICALS: PART IV. SOME REACTIONS OF TRIFLUOROIODOMETHANE WITH ALKYL ARSINES

WR Cullen

Index: Cullen,W.R. Canadian Journal of Chemistry, 1962 , vol. 40, p. 426 - 430

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Citation Number: 4

Abstract

Trifluoroiodomethane reacts with triethyl-and tri-n-butylarsine, and tri-n-butylphosphine to give products of the type R2MCF3. Heptafluoroiodopropane reacts similarly with trimethylarsine. Trifluoroiodomethane also reacts with the compounds (CH3) 2AsX (X= C6H5, Cl, I) and CH3AsI2 to give CH3As (CF3) 2; and in most of these reactions the compound CH3As (CF3) I is also formed, which is converted to the compound CH3As ( ...