Chelating ligands for nanocrystals' surface functionalization

C Querner, P Reiss, J Bleuse…

Index: Querner, Claudia; Reiss, Peter; Bleuse, Joel; Pron, Adam Journal of the American Chemical Society, 2004 , vol. 126, # 37 p. 11574 - 11582

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Citation Number: 165

Abstract

A new family of ligands for the surface functionalization of CdSe nanocrystals is proposed, namely alkyl or aryl derivatives of carbodithioic acids (RC (S) SH). The main advantages of these new ligands are as follows: they nearly quantitatively exchange the initial surface ligands (TOPO) in very mild conditions; they significantly improve the resistance of nanocrystals against photooxidation because of their ability of strong chelate-type binding ...