Tetrahedron letters

Palladium-catalyzed decarbonylation of tricyclic bridgehead acid chlorides

K Hori, M Ando, N Takaishi, Y Inamoto

Index: Hori, Kimihiko; Ando, Masatomo; Takaishi, Naotake Tetrahedron Letters, 1986 , vol. 27, # 38 p. 4615 - 4618

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Citation Number: 10

Abstract

Summary: Decarbonylation of tricyclic bridgehead acid chlorides 1 and 4 with palladium catalyst in the presence of tri-n-butylamine proceeded at 13O-OC to give exclusively stable disubstituted olefins 3 and 6, with probable intermediacy of the bridgehead olefins 2 and 5, respectively.