The Preparation of Some β-Sulfonylacrylate Thioesters and β-Sulfonylvinyl Ketones

RK Haynes, SC Vonwiller, JP Stokes…

Index: Haynes, Richard K.; Vonwiller, Simone C.; Stokes, John P.; Merlino, Louisa M. Australian Journal of Chemistry, 1988 , vol. 41, # 6 p. 881 - 895

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Citation Number: 16

Abstract

Abstract β-Sulfonylacrylate phenyl and t-butyl thioesters, and β-sulfonylvinyl ketones have been prepared by oxidation of the corresponding β-aryl-and β-alkyl-thio compounds. In one case the β-sulfonylvinyl ketone was obtained from an epoxy sulfone. The β-aryl-and β-alkyl- thio compounds were obtained by chlorination-dehydrochlorination of saturated precursors. The reactions of 3-(phenylthio) propionyl chloride with organocadmium and Grignard ...