Catalytic hydrophosphination of styrenes
MO Shulyupin, MA Kazankova, IP Beletskaya
Index: Shulyupin, Mstislav O.; Kazankova, Marina A.; Beletskaya, Irina P. Organic Letters, 2002 , vol. 4, # 5 p. 761 - 763
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Citation Number: 128
Abstract
The first example of intermolecular hydrophosphination of styrenes catalyzed by Ni and Pd complexes is described. The reaction of Ph2PH with styrene, 4-vinylpyridine, 2-vinylpyridine, 4-methoxystyrene, 2-methoxystyrene, and 5-vinyl-2-methylpyridine in benzene under Ni [P (OEt) 3] 4 catalysis proceeds with high yield and selectivity to give only anti-Markovnikov product.
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