Die Beständigkeit von (η 5-C 5 H 4 R) 2 Ti (C CR′) 2 in Abhängigkeit von den elektronischen Eigenschaften der Cyclopentadienyl-Liganden. Die Festkörperstruktur …
…, E Meichel, T Stein, S Back, E Hovestreydt
Index: Lang; Meichel; Stein; Back; Hovestreydt Journal of Organometallic Chemistry, 2001 , vol. 633, # 1-2 p. 71 - 78
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Abstract
The synthesis of the titanocene dichlorides (η5-C5H5)(η5-C5H4SiMe3) TiCl2 (3) and (η5- C5H4CO2R) 2TiCl2 (8a, R= CH3; 8b, R= CH2CH3), which contain either electron-donating or electron-withdrawing substituents at the cyclopentadienyl fragments is discussed. While the reaction of 8a or 8b with LiC CR′ in different stoichiometric ratios leads only to product mixtures from which no pure components could be isolated, treatment of 3 with ...
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