A Purely Organic Molecular Metal Based on a Hydrogen??Bonded Charge??Transfer Complex: Crystal Structure and Electronic Properties of TTF??Imidazole–p?? …

…, K Sato, D Shiomi, T Takui, M Maesato…

Index: Murata, Tsuyoshi; Morita, Yasushi; Fukui, Kozo; Sato, Kazunobu; Shiomi, Daisuke; Takui, Takeji; Maesato, Mitsuhiko; Yamochi, Hideki; Saito, Gunzi; Nakasuji, Kazuhiro Angewandte Chemie - International Edition, 2004 , vol. 43, # 46 p. 6343 - 6346

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Citation Number: 95

Abstract

The control of the relative molecular orientation of redoxactive molecules is of great importance for constructing organic conductors and superconductors.[1] Ingenious manipulation of noncovalent interactions such as hydrogen bonding (H-bonding) is an efficient tool for creation of desired molecular arrangements.[2] Thus, a variety of tetrathiafulvalene (TTF) derivatives with H-bonding functionality have been synthesized.[3] ...