Stereocontrolled total synthesis of the triquinane marine sesquiterpene Δ9 (12)-capnellene
LA Paquette, KE Stevens
Index: Paquette, Leo A.; Stevens, Kenneth E. Canadian Journal of Chemistry, 1984 , vol. 62, p. 2415 - 2420
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Citation Number: 18
Abstract
A total synthesis of Δ9 (12)-capnellene, a cis-anti-cis-tricyclo [6.3. 0.02, 6] undecane sesquiterpene of marine origin, is described. Starting with bicyclic enone 5, which was prepared by a Nazarov cyclization, the remaining portion of the molecule is elaborated by
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