The Journal of Organic Chemistry

Solvolyses of 3-oxo-and 3-methylenebicyclo [2.2. 2] oct-1-yl triflates: through-bond interaction of a. beta.-carbonyl lone pair with a cationic p orbital

M Yoshida, K Takeuchi

Index: Yoshida, Masayasu; Takeuchi, Ken'ichi Journal of Organic Chemistry, 1993 , vol. 58, # 9 p. 2566 - 2572

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Citation Number: 16

Abstract

Results Synthesis of Solvolysis Substrates. The 2-oxo, 2-methylene, and parent bridgehead triflates (lb, 2b, 6b, and 7b) were described previously. 8 The 3-oxo and 3-methylene bridgehead triflates (3b, 4b, and 5b) were synthesized as follows (Schemes I11 and IV).

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