Reaction pathways of zirconocene-catalyzed silylation of alkenes with chlorosilanes
J Terao, Y Jin, K Torii, N Kambe
Index: Terao, Jun; Jin, Yingshi; Torii, Kazushi; Kambe, Nobuaki Tetrahedron, 2004 , vol. 60, # 6 p. 1301 - 1308
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Citation Number: 15
Abstract
Reaction pathways as well as stereochemistries and stoichiometries of zirconocene- catalyzed silylation of olefins with chlorosilanes in the presence of nBuMgCl were studied and discussed in detail. Rate determining steps were examined by kinetic studies and labeling experiments.
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