Liebigs Annalen der Chemie

Zur Stereochemie der Phosphat??Phosphonat??Umlagerung

F Hammerschmidt, H Völlenkle

Index: Hammerschmidt, Friedrich; Voellenkle, Horst Liebigs Annalen der Chemie, 1986 , # 12 p. 2053 - 2064

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Citation Number: 14

Abstract

Abstract Die enantiomerenreinen 1-Phenylethanole (R)-(+)-5 und (S)-(−)-5 wurden in die Diethylphosphate (R)-(+)-6 bzw.(S)-(−)-6 übergeführt, die einer Phosphat-Phosphonat- Umlagerung zu den 1-Hydroxyphosphonaten (−)-7 bzw.(+)-7 unterworfen wurden. Die ...

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