Rate constants for abstraction of hydrogen from benzene, toluene, and cyclopentane by methyl and ethyl radicals over the temperature range 650-770 K
HX Zhang, SI Ahonkhai…
Index: Zhang, H.-X.; Ahonkhai, S. I.; Back, M. H. Canadian Journal of Chemistry, 1989 , vol. 67, p. 1541 - 1549
Full Text: HTML
Citation Number: 41
Abstract
Rate constants for the abstraction of hydrogen from benzene, toluene, and cyclopentane by methyl and ethyl radicals have been measured relative to the corresponding abstraction reaction from ethylene. The method is based on the effect on the rates of formation of methane and ethane of the addition of small quantities of the reactants to the thermal chain reactions of ethylene in the temperature range 650-770 K. Taking the following values of ...
Related Articles:
[Malatesta, V.; Ingold, K. U. Journal of the American Chemical Society, 1981 , vol. 103, # 3 p. 609 - 614]
Heats of formation of some simple alkyl radicals
[Castelhano, A. L.; Griller, D. Journal of the American Chemical Society, 1982 , vol. 104, # 13 p. 3655 - 3659]
[Minozzi, Matteo; Nanni, Daniele; Walton, John C. Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 2056 - 2069]
A kinetic study of the reactions of tert-butoxyl with alkenes: hydrogen abstraction vs. addition
[Wong, P. C.; Griller, D.; Scaiano, J. C. Journal of the American Chemical Society, 1982 , vol. 104, # 19 p. 5106 - 5108]
The free radical reaction between alkanes and carbon tetrachloride
[Hawari, J. A.; Davis, S.; Engel, P. S.; Gilbert, B. C.; Griller, D. Journal of the American Chemical Society, 1985 , vol. 107, # 16 p. 4721 - 4724]