On the mechanism of allylic amination catalyzed by iron salts
RS Srivastava, KM Nicholas
Index: Srivastava, Radhey S.; Nicholas, Kenneth M. Journal of the American Chemical Society, 1997 , vol. 119, # 14 p. 3302 - 3310
Full Text: HTML
Citation Number: 75
Abstract
Iron salts catalyze the allylic amination of alkenes by arylhydroxylamines in moderate to good yields and with high regioselectivity resulting from double-bond transposition. The iron- catalyzed reaction of phenylhydroxylamine with representative alkenes in the presence of 2, 3-dimethylbutadiene, an effective PhNO trap, produces allyl amines exclusively, excluding the intermediacy of free PhNO in the amination reaction. The reaction of FeCl2, 3 with ...
Related Articles:
Photoassisted, iron-catalyzed allylic amination of olefins with nitroarenes
[Srivastava, Radhey S.; Kolel-Veetil, Manoj; Nicholas, Kenneth M. Tetrahedron Letters, 2002 , vol. 43, # 6 p. 931 - 934]
Iron??Catalyzed Allylic C–H Amination of Substituted 1, 3??Dienes
[Murru, Siva; Srivastava, Radhey S. European Journal of Organic Chemistry, 2014 , vol. 2014, # 10 p. 2174 - 2181]
Transition metal catalyzed reactions of allene
[Coulson,D.R. Journal of Organic Chemistry, 1973 , vol. 38, p. 1483 - 1490]