Approach for the Preparation of Various Classes of Peroxides Based on the Reaction of Triketones with H2O2: First Examples of Ozonide Rearrangements

IA Yaremenko, AO Terent'ev, VA Vil…

Index: Antonovskii, V. L.; Fedorova, E. V.; Shtivel', N. E.; Emelin, Yu. D. Journal of Organic Chemistry USSR (English Translation), 1991 , vol. 27, # 4 p. 704 - 706 Zhurnal Organicheskoi Khimii, 1991 , vol. 27, # 4 p. 820 - 823

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Citation Number: 9

Abstract

Abstract The reaction of β, δ-triketones with an ethereal solution of H 2 O 2 catalyzed by heteropoly acids in the presence of a polar aprotic co-solvent proceeds via three pathways to form three classes of peroxides: tricyclic monoperoxides, bridged tetraoxanes, and a pair