Alkaline metal fluorides in graphite-new catalysts in organic synthesis. I. Reactions of polyfluoroaromatic compounds with O-and N-nucleophilic agents

…, VI Danilkin, PP Rodionov, GN Shnitko

Index: Aksenov, V. V.; Vlasov, V. M.; Danilkin, V. I.; Rodionov, P. P.; Shnitko, G. N. Journal of Fluorine Chemistry, 1990 , vol. 46, # 1 p. 57 - 73

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Citation Number: 6

Abstract

Abstract The paper reports the use of new catalysts-alkaline metal fluorides in graphite of the general formula C 8 MF, where M= Li, Na, K, Rb or Cs, in the reactions of polyfluoroaromatic compounds with aromatic OH-acids and piperidine. These compounds are shown to have a high activity in the above processes, exceeding that of similar free fluorides of alkaline metals.