Fluorination with caesium fluoroxysulphate. Part XI.: Mild functionalization of saturated hydrocarbons
S Stavber, M Zupan
Index: Stavber, Stojan; Zupan, Marko Tetrahedron, 1989 , vol. 45, # 9 p. 2737 - 2742
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Citation Number: 18
Abstract
Several hydrocarbons reacted with caesium fluoroxysulphate in acetonitrile at 35° C yielding mono and disubstituted products. Fluorocyclohexane, fluorocycloheptane, and 2-exo- fluoronorbornane formed in the reactions with the corresponding hydrocarbons were accompanied by up to 15% of other unidentified fluoro products, but their amount was strongly diminished when fluorination was performed in the presence of nitrobenzene. ...
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