Preparation and reaction of tert-butyl trimethylsilyl carbonate and related compounds

DS Tarbell, Y Yamamoto

Index: Yamamoto,Y.; Tarbell,D.S. Journal of Organic Chemistry, 1971 , vol. 36, p. 2954 - 2956

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Citation Number: 12

Abstract

tert-Butyl trimethylsilyl carbonate (4a) and the thiol analog 3 have been prepared from the corresponding tert-butyl carbonate salts and chlorotrimethylsilane. Similar compounds were prepared with primary and secondary alkyl groups; the n-butyl compound proved to be too unstable to isolate, but the ethyl analog was obtained pure. The compounds 3 and 4 react with a variety of secondary and primary amines to form the silylcarbamates 5. Action of ...