Grignard Reagents of Sulfones. VIII. Reactions of Alkylene Disulfones with Ethylmagnesium Bromide1

L Field, ET Boyd

Index: Field,L.; Boyd,E.T. Journal of Organic Chemistry, 1964 , vol. 29, p. 3273 - 3276

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Citation Number: 3

Abstract

Reactions were studied between ethylmagnesium bromide and alkylene disulfones of the structure ArSOz-(CH2), S02Ar. With n= 2, no stable metalated product could be demonstrated by addition to benzaldehyde, but the presence of such a product could not be altogether discounted; vigorous conditions resulted in difficultly reproducible elimination and reduction reactions which gave mixtures of products. With n= 5, formation of bis-Grignard ...